Here's what I know:
Most early ECUs (with the "PRC" part numbers) have the PROM soldered in place. It's only in a socket on later units -- I believe this includes all "AMR" ECUs, and I've heard that some later PRCs have socketed PROMs as well.
Note that 1989 model year NAS Land Rovers used the 14CU system, as the 14CUX wasn't introduced until 1990. The 14CU lacks the wiring in the harness used by the external fault code display module. It also lacks the wiring used by the "tune resistor" (intended to allow selection of the fuel map), although this doesn't matter because the NAS firmware disables support for the tune resistor anyway. NAS firmware is hardcoded to use map #5. The 14CUX systems also use updated fuel injectors that offer slightly better fuel economy.
I've never tried to swap a 14CU PROM into a 14CUX system, but I can't think of any reason it wouldn't work. Most of the upgrades over years of 14CU(X) production (such as the improvement for cold-weather start) are handled by the firmware in the PROM.
--Colin